THE ELEMENT WITH CONSTANT PHASE SHIFT IN GALVANODYNAMIC MODE

Abstract: the purpose of this study is to study the behavior of the boundary perfectly polarized electrode – solid electrolyte in the presence of a constant phase shift impedance (CPS) in the galvanic-dynamic mode.

Analytical expressions of the dependence of the potential of the interface of an ideally polarizable electrode-solid electrolyte on time in the galvanodynamic mode in 2 cases are obtained: 1) in the case of a full equivalent electrical circuit; 2) in the case of a reduced equivalent electrical circuit. The complete coincidence of analytical expressions for the potential of the interphase boundary in both cases is shown.

Keywords: ideal-polarizable electrode, solid electrolyte, constant phase shift impedance, equivalent electrical circuit, galvanodynamic mode