English
Русский 46-55 p.
The study aims to create biodegradable composite materials based on non-emulsion polymer latexes with natural fillers. The article provides an analysis of the current state of the issue on the methods of obtaining and the state of the market of biodegradable polymer materials. The results of research on the development of a method for obtaining biodegradable polymer materials based on 1,4-cis-polyisoprene non-emulsion polymer latexes are presented. The paper develops recipes for the obtaining of artificial latex of isoprene rubber, a latex composition based on it, and also experimentally determines such technological parameters as the concentration of coagulant, the dipping mode of porcelain molds, the drying temperature of latex gel and vulcanization of films. During research has been proved the ability of the created polymer composite products to biodegradation under the influ-ence of biotic factors. Stimulation of biodegradation processes occurs due to the natural fillers of wood flour and coffee oil cake introduced at the latex stage in the form of pre-prepared suspensions. The developed technology makes it possible to obtain, using the method of coagulant sedimentation, composite polymer thin-film materials with adjustable operating time, makes it possible to reduce the load on the environment after the disposal of used products by burying them into the soil at polygons. The obtained polymer composite materials can be used to ob-tain dipped articles, for example, gloves for household, pharmaceutical, and chemical purposes.
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2. Dmitrienko V.P. i dr. Ocenka ekologicheskoj bezopasnosti termoplastichnyh materialov na osnove linejnyh polimerov. Ekologiya promyshlennogo proizvodstva. M.: Izd-vo «Kompas», 2018. № 1. S. 52 – 59.
3. Potapova E.V. Problema utilizacii plastikovyh othodov. Izvestiya Bajkal'skogo gosudarstvennogo universtiteta. Irkutsk: Izd-vo BGU, 2018. № 4. S. 535 – 544. DOI 10.17150/2500-2759.2018.28(4).535-544
4. Pipiya L.K., Dorogokupec V.S., Osipova O.E., SHashkova N.V., Hohlova V.A. Pererabotka plastmass: ocenka rynka i perspektivy. Nauka za rubezhom. M.: Izd-vo RAN, 2018. № 75. 33 s.
5. Volova T.G. Razrushaemye mikrobnye poligidroksialkanoaty v kachestve tekhnicheskogo analoga nerazrushaemyh poliolefinov. ZHurnal Sibirskogo federal'nogo universiteta. Biologiya. Krasnoyarsk: Izd-vo SFU, 2015. № 2. S. 131 – 151. DOI: 10.17516/1997-1389-2015-8-2-131-151.
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8. Susheel K., Biodegradable green composites / Susheel Kalia. Hoboken: Jonh Wiley & Sons, 2016. 380 p.
9. Rogovina S.Z. Biorazlagaemye polimernye kompozicii na osnove sinteticheskih i prirodnyh polimerov razlichnyh klassov. Vysokomolekulyarnye soedineniya. M.: Izd-vo Inst-t neftekhim. sinteza, RAN, 2016. № 1. S. 68 – 80. DOI: 10.17516/1997-1389-2015-8-2-131-151
10. Buryak V.P. Biopolimery – nastoyashchee i budushchee. Polimernye materialy. 2005. № 12. S. 22 – 27.
11. Pat. 2352597 Rossijskaya Federaciya, MPK C 08 L 23/02, C 08 L 23/10, C 08 L 101/16, C 08 J 3/22, C 08 L 3/20. Biorazlagaemaya granulirovannaya poliolefinovaya kompoziciya i sposob ee polucheniya Patentoobladatel': A.N. Ponomarev; zayavl. 25.06.2008; opubl. 20.04.2009.
12. Ioanna Kyrikou, Demetres Briassoulis Biodegradation of Agricultural Plastic Films: A Critical Review. Springer Science+Business Media, LLC 2007. P. 131 – 133. DOI 10.1007/s10924-007-0053-8
13. Anu Kapanen, Evelia Schettini, Giuliano Vox, Merja Ita¨vaara. Performance and Environmental Impact of Biodegradable Films in Agriculture: A Field Study on Protected Cultivation. Springer Science+Business Media, LLC 2008. P. 110 – 112. DOI 10.1007/s10924-008-0091-x
14. Gotlib E.M., Golovanova K.V., Selekhova A.A. Puti sozdaniya biorazlagaemyh polimernyh materialov i ih poluchenie na osnove plastificirovannyh diacetatov cellyulozy: monografiya. Kazan': KNITU, 2011. 132 s
15. Parmuhina E.L. Rossijskij rynok biorazlagaemoj upakovki. Ekologicheskij vestnik Rossii. M., 2011. S. 46 – 48.
16. Korotneva I.S., Muhin A.S., Dmitriev K.E. Tekhnologiya polucheniya biodestruktiruemyh polimernyh plenok na osnove iskusstvennyh lateksov sinteticheskih polimerov i prirodnyh napolnitelej. Mezhdunarodnaya nauchno-prakticheskaya konferenciya «Obrazovanie, nauka i tekhnologii: aktual'nye voprosy, innovacii i dostizheniya». M., 2020. S. 279 – 282.
17. Dmitriev K.E, Muhin A.S., Korotneva I.S., Solov'ev M.E. Kinetika biorazlozheniya polimernyh kompozicij na osnove poliizoprena. Sem'desyat chetvertaya vserossijskaya nauchno-tekhnicheskaya konferenciya studentov, magistrantov i aspirantov vysshih uchebnyh zavedenij s mezhdunarodnym uchastiem: sbornik materialov konferencii. YAroslavl': Izd-vo YAGTU, 2021. CH. 1. 999 s.