Strokova V.V.

Doctor of Engineering Sciences (Advanced Doctor), Professor, Belgorod State Technological University

EVALUATION OF EMULSIFIER EFFECT ON THE PROPERTIES OF WATER-BASED ALKYD EMULSION

Abstract
The study is devoted to the issue of evaluating the effect of an emulsifier on the properties of the developed water-based alkyd emulsion intended for dust suppression. The goal was to establish a rational ratio of components in this system according to the following criteria: a decrease in the average droplet size, a decrease in relative viscosity, and an increase in sedimentation stability (emulsion life). The components of the basic composition of the emulsion were alkyd varnish (Resin GF-0123), surfactant (AMP-95), distilled water. To analyze the obtained compositions of the alkyd emulsion, dispersions were prepared containing: alkyd – 55-75% with a step of 5%; Surfactant – 0.1-0.5% in increments of 0.1% of the alkyd content (in-stead). The emulsion was obtained under the following technological parameters: emulsification temperature – 35°C, emulsification speed – 5000 rpm. The analyzed parameters were: dispersion (droplet size), viscosity, life (sedimentation stability) of the emulsion. It has been established that a rational composition, at which the minimum values of dispersion and viscosity are achieved, with a high lifetime at the maximum content of the polymer component, is a composition that includes: 59.7% alkyd, 40% water and 0.3% surfactant. The developed composition makes it possible to obtain an emulsion with a lifetime of more than 1 month, an av-erage dispersion value of 3 µm, and a viscosity of 40 mPa·s.
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THE JOINT INFLUENCE OF SUCCAROSE AND HIGHLY DISPERSED CALCIUM HYDROSILICATES ON THE STRENGTH DEVELOPMENT KINETICS OF CEMENT CONCRETE

Abstract
Сement hydration accelerator (highly dispersed calcium hydrosilicates) and hydration retarder (sucrose) are components of calcium silicate dispersion (CSD). Their joint influence on the processes of setting and hardening of cement composites is considered. The content of 10% CSD in the composition of the composite binder (CB) leads to a shift of the thermal maximum on the thermokinetic curve by a day. At the same time, at the late stages of hydration (>70 hours), the heat release rate remains consistently high, it is 2-3 times higher than the heat release rate of the control sample. The setting kinetics of CB pastes depends on the content of CSD in its composition and is of an extreme nature. The effectiveness of CSD in the composition of CB was evaluated on the example of ordinary heavy concrete (B25) with the replacement of cement with CSD. The results of assessing the change in the strength of concrete at CB are supplemented with calculated strength indicators in the future up to 1800 days hardening. The expected compressive strength of concrete samples on a composite binder is 1.8 times higher than the strength of the control sample.
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