Keywords: collagen

STRUCTURE OF IONITE SYNTHESIZED ON THE BASIS OF PHENOL-FORMALDEHYDE RESIN AND DERMAL COLLAGEN HYDROLYSATE

Abstract
An ion-exchange weakly acid phenol-formaldehyde resin capable of adsorbing heavy metals has been synthesized. A new material, dermal collagen hydrolysate, was used as a resin modifier to impart ion–exchange properties. IR and EPR spectroscopy methods have established that the active centers of the sorbent obtained are carboxyl and amino groups. It is assumed that the presence of amino groups increases the sorption capacity under normal temperature conditions. By EPR spectroscopy, it was found that the adsorbed heavy metal ion becomes in an axial position.
Using an electron microscope, it was found that a decrease in the liquid coefficient (LC) of the hydrolysate leads to an increase in the porosity of the ionite (up to LC8), resulting in an increase in the sorption capacity, with a further decrease in the liquid coefficient, it is likely that the number of hydrolyzed protein molecules is sewn into the resin structure with a frequency sufficient to prevent pore formation. According to studies of the ionite surface, the synthesized ionite can be attributed to macroporous cationites – the ionite pore size reaches 37.3 microns.
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PRODUCTION OF PHENOL-FORMALDEHYDE SORBENTS FROM LEATHER INDUSTRY WASTE

Abstract
The leather industry refers to material-intensive industries in which the cost of raw materials is about 70-80% of the cost of finished products, therefore, the rational use of raw materials through waste disposal is of particular importance. 40-50% of the area can be used, the rest is usually sent for burial or incineration. Both in the first and in the second case, this is not only economically inefficient, but also an environmentally hazardous way to get rid of these wastes. One of the ways to dispose of such waste (minnow and sawn trim) is to process them into hydrolysates and use them in the production of gelatin, adhesives and building materials. In this paper, the possibility of using collagen hydrolysates as a modifier of phenol-formaldehyde resins has been studied. The sorption of heavy metal ions by an oligomeric sorbent obtained by modifying phenol-formaldehyde resins with collagen hydrolysate was studied at various pH values, temperature, particle sizes, and metal ion concentrations. The physical and technical characteristics of the adsorbent are determined.
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