English
Русский 31-39 p.
The paper presents the material devoted to the development of the concept of optimized technology for the production of molybdenum (tungstates) elements of the d-family (Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd and Ag) at a relatively low temperature, based on the model of a physico-chemical system, in which it is possible to form a thermally unstable intermediate phase – donor of high-defect oxide d-element, entering at the time of its formation into chemical interaction with thermally activated Mo(W)O3 with the formation of MeMo(W)O4.
In the process of solving the problem of finding the necessary to achieve the goal of the real prototypes of the chosen model of the physico-chemical system, taking into account the properties of reagents and products of their interaction, and in particular, the thermal instability of carbonates d-elements (their average decomposition temperature 3000C), it was concluded that they can be a system such as MeSO4-Na2CO3-Mo(W)O3, which was justified and confirmed in the laws of physico-chemical analysis, thermodynamics, chemical kinetics, theories of polarization of Nekrasov ions, acids and Lewis's grounds and confirmation in the experiment.
In the process of solving the problem of finding the necessary to achieve the goal of the real prototypes of the chosen model of the physico-chemical system, taking into account the properties of reagents and products of their interaction, and in particular, the thermal instability of carbonates d-elements (their average decomposition temperature 3000C), it was concluded that they can be a system such as MeSO4-Na2CO3-Mo(W)O3, which was justified and confirmed in the laws of physico-chemical analysis, thermodynamics, chemical kinetics, theories of polarization of Nekrasov ions, acids and Lewis's grounds and confirmation in the experiment.
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4. Pancake-like Fe2(MoO4)3 microstructures: microwave-assisted hydrothermal synthesis, magnetic and photocatalytic properties / Lei Zhang, Xiao-Feng Gao, Jing-Li Ma, Xue-Tu Chen and Zi-Ling Xue // New J. Chem. 2010. V. 34. P. 2027 – 2033.
5. Razrabotka racional'nogo sposoba sinteza nanokristallicheskogo molibdata Fe (3+) na osnove sistemy Fe2(SO4)3 – Na2SO3 – MoO3 / G.K. SHurdumov, Z.A. Abazova, YU.L. Kardanova, B.K. SHurdumov // 21 vek: fundamental'naya nauka i tekhnologii: Materialy mezhdunarodnoj nauchno-prakticheskoj konferencii. 10-11 noyabrya 2014 g. North Charleston USA. S. 172 – 176.
6. SHurdumov G.K., Tlimahova E.H., SHurdumov B.K. Sintez vol'framata kobal'ta v rasplavah sistemy (K2WO4-KCl)ehvt-CoSO4 ZHurn. neorgan. himii. 2010. T.55.№9. S. 1568-1572.
7. Modelirovanie kinetiki processov vosstanovleniya uglerodom vol'framatov nikelya i kobal'ta / N.V. Labuhova, A.D. Verhoturov, I.E. Ablesimov, I.F. Karpovich // EHlektronnyj zhurnal. «Issledovano v Rossii». S. 2283 – 2292.
8. SHurdumov G.K., Tlimahova E.H. Sintez v rasplavah sistemy (K2WO4-KCl)ehvt.-NiSO4 (K,Ni//Cl,SO4,WO4) vol'framat nikelya v vysokodispersnom sostoyanii // Izvestiya VUZov. Himiya i himicheskaya tekhnologiya. 2009. T. 52. №11. S. 11 – 15.
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11. Fiziko-himicheskoe issledovanie katalizatorov okislitel'nogo degidrirovaniya izobutana – molibdatov kobal'ta, nikelya i marganca / YU.A. Agafonov, N.V. Nekrasov, N.A. Gajdaj, M.A. Botavina i dr. // Kinet. I kataliz. 2009. T. 50. №4. S. 599 – 604.
12. Photoluminescent rroperties of CoMoO4 nanorods quickly synthesized and annealed in a domestic microwave oven / Ana P. de Moura, Larissa H. de Oliveira, Paula F.S. Pereira, Ieda L.V. Rosa and ets. // Advances in Chemical engineering and Science. 2012. №2. R. 465 – 473.
13. Lebuhova N.V., Karpovich N.F. Ugletermicheskoe vosstanovlenie oksidov i molibdatov medi, nikelya i kobal'ta // Neorgan. mater. 2008. T. 44. №8 S. 1003 – 1006.
14. Tverdofaznyj sintez vol'framata medi na osnove sistemy CuSO4 – Na2CO3 – WO3. / G.K. SHurdumov, YU.L. Kardanova, K.A. Buzdov, B.K. SHurdumov // Himiya v interesah ustojchivogo razvitiya. 2015. T. 3. №3. S. 291 – 298.
15. Ovechkin A.E., SHolkin A.R., Minkov B.I. Fotoprovodimost' i lyuminescenciya kristallov vol'framata kadmiya i vol'framata cinka // Lyuminescentnye priemniki i preobrazovateli ioniziruyushchego izlucheniya: Mater. 6 Vses. Simp. L'vov. 26-28 avg. 1988. L'vov. 1989. S. 151.
16. Lou Zhidong, Hao Jianhua, Cocivera Michael. Luminescence of ZnWO4 and CdWO4 thin perared by spay pyrolysis // J. Luminescence. 2002. V. 99. №4. P. 349 – 354.
17. Growing of 106CdWO4, ZnWO4, ZnMoO4. / E.N. Galahov, T.M. Denisov, I.M. Ivanov, E.P. Makarov and ets. // Scintillation crystals forrare events search by low thermal gradient Crochralskitechigue. Funct.: Mater. 2010. V. 17. №4. R. 504 – 508.
18. Guangli Huang, Chuan Zhang, Yangfa Zhu. ZnWO4 Photocatalyst with High Activity for Degradation Organic Contaminants. // J. Alloys and Compounds. 2007. V. 432. №1-2. P. 269 – 276.
19. SHurdumov G.K., Unezheva Z.H., Kardanova YU.L. Razrabotka racional'nogo sposoba sinteza vol'framata cinka v rasplavah sistemy (K2WO4-KCl)ehvt – ZnSO4 [K, Zn//Cl, SO4, WO4] // Rasplavy. 2015. №2. S. 101 – 112.
20. Poda D.V. Scintillating bolometers based on ZnMoO4 and Zn100MoO4 crystals to search for 0 ν 2β decay of 100Mo (LUMINEU project): first tests at the Modane Underground Laboratory. 37 th International Conferentional Conference of high Energyphysics. 2-7 July 2014. Valencia. P. 1 – 14.
21. Reut E.P. Spektral'naya zavisimost' sobstvennoj lyuminescencii molibdata kadmiya // Optika i spektroskopiya. 1996. №3. S. 426 – 429.
22. Opticheskie i lyuminescentnye svojstva scintillyatorov na osnove vol'framatov kadmiya i cinka / V.N. Kolobanov, V.N. Mahov, V.V. Mihajlin, D.A. Spasskij i dr. // Neorganicheskie materialy. 2001. T. 37. №1. S. 30 – 34.
23. Tret'yakov YU.D. Tverdofaznye reakcii M: Himiya, 1978. 360 s.
24. SHurdumov G.K., CHerkesov Z.A., Kerefov Z.O. Sintez vol'framata natriya na osnove sistemy Na2C2O4-NaNO3-WO3 // ZHurn. neorgan. himii. 2007. T. 52. №5. S. 739 – 742.
25. Bokij G.B. Kristallohimiya. M.: Nauka,1971. 400 s.
26. Nekrasov B.V. Osnovy obshchej himii. T. 2 M.: Himiya, 1973. 688 s.
27. Viting L.M. Vysokotemperaturnye rastvory-rasplavy. M.: Izd-vo MGU, 1991. 221 s.
2. Kinetika i mekhanizm okislitel'nogo degidrirovaniya izobutana na molibdatah Co, Ni, Mn. / YU.A. Agafonov, N.V. Nekrasov, N.A. Gajdaj i dr. // Kinet. i katal. 2007. T. 48. №2. S. 271 – 280.
3. Fotorazlozhenie metiloranzha na poroshkoobraznom vol'framate marganca v kachestve katalizatora pri ispol'zovanii razlichnyh istochnikov sveta pri raznyh znacheniyah pH / H.Y. He, J.F. Huang, L.Y. Cao, J.P. Wu // Desalination. 2010.T. 252. №1-3. S. 66 – 70.
4. Pancake-like Fe2(MoO4)3 microstructures: microwave-assisted hydrothermal synthesis, magnetic and photocatalytic properties / Lei Zhang, Xiao-Feng Gao, Jing-Li Ma, Xue-Tu Chen and Zi-Ling Xue // New J. Chem. 2010. V. 34. P. 2027 – 2033.
5. Razrabotka racional'nogo sposoba sinteza nanokristallicheskogo molibdata Fe (3+) na osnove sistemy Fe2(SO4)3 – Na2SO3 – MoO3 / G.K. SHurdumov, Z.A. Abazova, YU.L. Kardanova, B.K. SHurdumov // 21 vek: fundamental'naya nauka i tekhnologii: Materialy mezhdunarodnoj nauchno-prakticheskoj konferencii. 10-11 noyabrya 2014 g. North Charleston USA. S. 172 – 176.
6. SHurdumov G.K., Tlimahova E.H., SHurdumov B.K. Sintez vol'framata kobal'ta v rasplavah sistemy (K2WO4-KCl)ehvt-CoSO4 ZHurn. neorgan. himii. 2010. T.55.№9. S. 1568-1572.
7. Modelirovanie kinetiki processov vosstanovleniya uglerodom vol'framatov nikelya i kobal'ta / N.V. Labuhova, A.D. Verhoturov, I.E. Ablesimov, I.F. Karpovich // EHlektronnyj zhurnal. «Issledovano v Rossii». S. 2283 – 2292.
8. SHurdumov G.K., Tlimahova E.H. Sintez v rasplavah sistemy (K2WO4-KCl)ehvt.-NiSO4 (K,Ni//Cl,SO4,WO4) vol'framat nikelya v vysokodispersnom sostoyanii // Izvestiya VUZov. Himiya i himicheskaya tekhnologiya. 2009. T. 52. №11. S. 11 – 15.
9. Dyumaeva I.V., Mamed'yaeva K.B. Pervye katalizatory dlya polucheniya nitrilov // Sovremennye problemy istorii estestvoznaniya v oblasti himii, himicheskoj tekhnologii i neftyanogo dela: Materialy 3 Mezhdunarodnoj nauchnoj konferencii. Ufa. 2002. T. 1. Ufa: Reaktiv. 2002. S. 33 – 42.
10. Halawy Samich A. Nepromotirovannyj i promotirovannyj s pomoshch'yu K2O kobal'ta kak katalizatory dlya razlozheniya uksusnoj kisloty // Monatsh Chem. 2003. T. 134. №3. S. 371 – 380.
11. Fiziko-himicheskoe issledovanie katalizatorov okislitel'nogo degidrirovaniya izobutana – molibdatov kobal'ta, nikelya i marganca / YU.A. Agafonov, N.V. Nekrasov, N.A. Gajdaj, M.A. Botavina i dr. // Kinet. I kataliz. 2009. T. 50. №4. S. 599 – 604.
12. Photoluminescent rroperties of CoMoO4 nanorods quickly synthesized and annealed in a domestic microwave oven / Ana P. de Moura, Larissa H. de Oliveira, Paula F.S. Pereira, Ieda L.V. Rosa and ets. // Advances in Chemical engineering and Science. 2012. №2. R. 465 – 473.
13. Lebuhova N.V., Karpovich N.F. Ugletermicheskoe vosstanovlenie oksidov i molibdatov medi, nikelya i kobal'ta // Neorgan. mater. 2008. T. 44. №8 S. 1003 – 1006.
14. Tverdofaznyj sintez vol'framata medi na osnove sistemy CuSO4 – Na2CO3 – WO3. / G.K. SHurdumov, YU.L. Kardanova, K.A. Buzdov, B.K. SHurdumov // Himiya v interesah ustojchivogo razvitiya. 2015. T. 3. №3. S. 291 – 298.
15. Ovechkin A.E., SHolkin A.R., Minkov B.I. Fotoprovodimost' i lyuminescenciya kristallov vol'framata kadmiya i vol'framata cinka // Lyuminescentnye priemniki i preobrazovateli ioniziruyushchego izlucheniya: Mater. 6 Vses. Simp. L'vov. 26-28 avg. 1988. L'vov. 1989. S. 151.
16. Lou Zhidong, Hao Jianhua, Cocivera Michael. Luminescence of ZnWO4 and CdWO4 thin perared by spay pyrolysis // J. Luminescence. 2002. V. 99. №4. P. 349 – 354.
17. Growing of 106CdWO4, ZnWO4, ZnMoO4. / E.N. Galahov, T.M. Denisov, I.M. Ivanov, E.P. Makarov and ets. // Scintillation crystals forrare events search by low thermal gradient Crochralskitechigue. Funct.: Mater. 2010. V. 17. №4. R. 504 – 508.
18. Guangli Huang, Chuan Zhang, Yangfa Zhu. ZnWO4 Photocatalyst with High Activity for Degradation Organic Contaminants. // J. Alloys and Compounds. 2007. V. 432. №1-2. P. 269 – 276.
19. SHurdumov G.K., Unezheva Z.H., Kardanova YU.L. Razrabotka racional'nogo sposoba sinteza vol'framata cinka v rasplavah sistemy (K2WO4-KCl)ehvt – ZnSO4 [K, Zn//Cl, SO4, WO4] // Rasplavy. 2015. №2. S. 101 – 112.
20. Poda D.V. Scintillating bolometers based on ZnMoO4 and Zn100MoO4 crystals to search for 0 ν 2β decay of 100Mo (LUMINEU project): first tests at the Modane Underground Laboratory. 37 th International Conferentional Conference of high Energyphysics. 2-7 July 2014. Valencia. P. 1 – 14.
21. Reut E.P. Spektral'naya zavisimost' sobstvennoj lyuminescencii molibdata kadmiya // Optika i spektroskopiya. 1996. №3. S. 426 – 429.
22. Opticheskie i lyuminescentnye svojstva scintillyatorov na osnove vol'framatov kadmiya i cinka / V.N. Kolobanov, V.N. Mahov, V.V. Mihajlin, D.A. Spasskij i dr. // Neorganicheskie materialy. 2001. T. 37. №1. S. 30 – 34.
23. Tret'yakov YU.D. Tverdofaznye reakcii M: Himiya, 1978. 360 s.
24. SHurdumov G.K., CHerkesov Z.A., Kerefov Z.O. Sintez vol'framata natriya na osnove sistemy Na2C2O4-NaNO3-WO3 // ZHurn. neorgan. himii. 2007. T. 52. №5. S. 739 – 742.
25. Bokij G.B. Kristallohimiya. M.: Nauka,1971. 400 s.
26. Nekrasov B.V. Osnovy obshchej himii. T. 2 M.: Himiya, 1973. 688 s.
27. Viting L.M. Vysokotemperaturnye rastvory-rasplavy. M.: Izd-vo MGU, 1991. 221 s.