THE ELEMENT WITH CONSTANT PHASE SHIFT IN GALVANODYNAMIC MODE

The purpose of this study is to study the behavior of the boundary perfectly polarized electrode – solid electrolyte in the presence of a constant phase shift impedance (CPS) in the galvanic-dynamic mode.
Analytical expressions of the dependence of the potential of the interface of an ideally polarizable electrode-solid electrolyte on time in the galvanodynamic mode in 2 cases are obtained: 1) in the case of a full equivalent electrical circuit; 2) in the case of a reduced equivalent electrical circuit. The complete coincidence of analytical expressions for the potential of the interphase boundary in both cases is shown.
1. Ukshe E.A., Bukun N.G. Tverdye elektrolity. M.:Nauka, 1977. 175 s.
2. Gusejnov R.M. Relaksacionnye processy v tverdyh elektrolitah. M..: Nauka, 1993. 160 s.
3. Bronin D.I. Elektrohimicheskie svojstva granicy razdela zhidkij metall – oksidnyj elektrolit 0,9ZrO2.0,1Y2O3: dis. … kand.him.nauk. Sverdlovsk, 1988. 187 s.
4. Zaharov V.A., Zembekov N.S., Zaharov A.V., Russkih I.T. Raschet central'nyh koefficientov namagnichivaniya cilindricheskih ferromagnitnyh sterzhnej pri nasyshchenii magnetika // Izvestiya vysshih uchebnyh zavedenij. Fizika. 2005. T. 48. № 4. S. 53 – 61.
5. Zaharov V.A., Zaharov A.V., Zembekov N.S., Russkih I.T. Uchet nekollinearnosti vektorov namagnichennosti pri raschyote magnitnyh polej v ferromagnitnyh cilindricheskih sterzhnyah // Izvestiya vysshih uchebnyh zavedenij. Fizika. 2005. T. 48. № 2. S. 63 – 69.