Tsygankov D.V.

Candidate of Chemical Sciences, Associate Professor, Kuzbass State Technical University named after T.F. Gorbachev

Formation of diesel fuel aerosols in the presence of propylene oxide and its derivatives

https://doi.org/10.58224/2619-0575-2025-8-4-8
Abstract
Studying the formation of diesel fuel aerosols in the presence of propylene oxide and its derivatives in a laboratory setup allows us to closely approximate the process of real-life mixture formation in diesel engines and determine the influence of these compounds on combustion efficiency and exhaust smoke.
Objective. To identify differences in the aerosol formation characteristics of diesel fuel without additives and diesel fuel containing propylene oxide and its derivatives as additives.
Methods. The method involves using a steam generator to generate aerosols and a high-speed video camera to capture all stages of aerosol formation. A high-speed CMOS video camera, "Phantom MIRO M310" (image type – 1080p), was used to record the process under study. monochrome; maximum resolution 1280×800 pixels; maxi-mum shooting speed – 6.5 105 fps; minimum exposure time – 1 μs; maximum image bit depth – 12 bits). A SIGMA 50 mm 1:2.8D MACRO EX lens (focal length – 50 mm, relative aperture – 2.8) was used for video recording. A Multiled PT-V9 GS Vitec LED illuminator (number of LEDs – 24; luminous flux – 7700 lm; power – 84 W, disper-sion angle – 30º) was used to illuminate the recording area. A matte polycarbonate screen (2 mm thick) was used to diffuse the light from the illuminator. The LED illuminator and CMOS video camera were placed opposite each other so that the optical axis of the camera coincided with the direction of the luminous flux of the illuminator.
Results and conclusions. Introduction into the diesel engine Adding 0.1% propylene oxide and its derivatives to fuel reduces the onset of intense fuel evaporation by up to two times. In a real engine, this effect will significantly reduce the size of liquid diesel fuel droplets in the cylinder, leading to more complete combustion and reduced soot formation. This results in increased power, reduced fuel consumption, and reduced exhaust smoke.
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Atomic refraction by oxygen as a method for assessing the activity of oxygenates for internal combustion engines

https://doi.org/10.58224/2619-0575-2025-8-1-4
Abstract
Relevance: it is proposed to evaluate the efficiency or activity of oxygenate compounds by the value of oxygen atomic refraction. This will allow developing new components and additives for the production of motor fuels based on available domestic raw materials.
Objective. Comparison of the efficiency of oxygenate additives and supplements using simple calculation meth-ods.
Methods: a calculation method for determining the molecular and atomic diffraction of oxygenates was used.
Results and conclusions: all oxygenate compounds contain oxygen and the lower the atomic refraction, the more active the vibrations of atoms and electrons in the molecules of oxygenate compounds. Thus, the lower the atomic refraction of oxygen, the higher the activity of the oxygenate. Both molecular and atomic refractions of the main oxygenates have been determined, which made it possible to compare the oxygenates in use and those with potential. An important point is the specific refraction per 1 gram of substance. It is also possible to compare the activity of oxygenates, but in the reverse order: the higher the specific refraction, the more effective the compound is for a spark-ignition engine. For diesel engines, it is desirable to have higher atomic refraction and lower specific refraction per 1 gram of substance, i.e. in the reverse order.
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