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Цель: являлось экспериментальное изучение влияния гамма-облучения в диапазоне поглощённых доз 25-200 кГр на физико-химические свойства твёрдых отходов транспортировки нефти по трубопроводам. Объектом исследования служили асфальтосмолопарафиновые отложения, отобранные при очистке магистрального нефтепровода. В ходе работы решались следующие задачи: количественное определение изменений группового углеводородного состава (масла, парафины, смолы, асфальтены) методом адсорбционной хроматографии; анализ молекулярно-массового распределения методом гель-проникающей хроматографии; оценка реологических характеристик (температура плавления, застывания, условная вязкость) и термической стабильности методом термогравиметрического анализа. Установлено, что при дозе 200 кГр содержание парафинов снижается в 1,65 раза, а асфальтенов возрастает в 1,8 раза, полидисперсность системы увеличивается с 6,56 до 10,72, условная вязкость при 80°C возрастает более чем вдвое, а коксовый остаток увеличивается с 3,5% до 8,2% масс. Практическая значимость результатов заключается в обосновании возможности использования радиационно-модифицированных отходов в качестве компонента битумных композиций с повышенной термостойкостью или сырья для получения углеродных материалов. Полученные данные могут быть использованы при разработке технологий утилизации нефтяных отходов с применением ионизирующего излучения.
1. Гулиева Н., Иманова Г., Мустафаев И. Влияние ионизирующих лучей на физико-химические свойства твёрдых отходов, образующихся в процессе транспортировки нефти через трубопроводы // Технологии излучения и их применение. 2023. P. 39 – 40.
2. Taheri A., Shirmardi S. P. Applications of ionizing irradiation in oil industry: a review // Reviews in Chemical Engineering. 2025. Vol. 41. № 3. P. 241 – 268.
3. Alshahrani B., Korna A.H., Fares S.S., Ali A.H., Salman M. Assessing radiological hazards from NORM in oil and gas production residues: a comprehensive study // Radiation Effects and Defects in Solids. 2025. Vol. 180. № 9-10. P. 1307 – 1330.
4. Nasr A.S., Duraia E.M., Shafaa M.W., Ayoub H.A., Essa A.M. Evaluation and characterization of the radiological environmental impact of waste generated from the oil ash // Journal of Radioanalytical and Nuclear Chemistry. 2024. Vol. 333. № 11. P. 5867 – 5879.
5. Gogolinskiy K. V. Vinogradova A.A., Kopylavaet T.N. Study of physicochemical properties of polyethylene gas pipelines material with a prolonged service life // International Journal of Pressure Vessels and Piping. 2022. Vol. 200. P. 104825 – 104836.
6. Tanhaei H., Saeedi Dehaghani A. H. Improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing // Scientific Reports. 2025. Vol. 15. № 1. P. 7434.
7. Morales-Hidalgo M., Povedano-Priego C., Martinez-Moreno M.F., Ruiz-Fresneda M.A., Lopez-Fernandez M., Jroundi F., Merroun M.L. Insights into the impact of physicochemical and microbiological parameters on the safety performance of deep geological repositories // Microorganisms. 2024. Vol. 12. № 5. P. 1025.
8. Joledo A.O., Orosun M.M., Ademola T. Radiological impact assessment of produced water from oilfield production facilities in the Niger Delta region // Nuclear Analysis. 2025. Vol. 4. №. 2. P. 100174.
9. Oliveira H., Pinheiro I., Ramos A., Venturini O., Mariano A., Santiago Y. Influence of physicochemical properties of oil sludge on syngas production for energy applications. Resources. 2024. Т. 14. № 1. P. 8 – 15.
10. Tang L., Wang T., Xu Y., He X., Yan A., Zhang Z., Li Y., Chen G. Research and application progress of crude oil demulsification technology // Processes. 2024. Vol. 12. № 10. P. 2292.
11. Guerrero-Martin C.A., Ortega-Ramírez A.T., Perilla Rodríguez P.A., Reyes López S.J., Guerrero-Martin L.E., Salinas-Silva R., Camacho-Galindo S. Analysis of environmental sustainability through a weighting matrix in the oil and gas industry // Sustainability. 2023. Vol. 15. № 11. P. 9063.
12. Elkatory M., Soliman E., Hassaan M., Ali R., Hafez E., Ibrahim H. S., Hashem A. Chemical mitigation technology for wax deposition in submarine oil pipeline systems // Egyptian Journal of Chemistry. 2021. № 64 (10). P. 5989 – 5997.
13. Lu Y., Zhu Y., Yang F., Xu Z., Liu Q. Advanced switchable molecules and materials for oil recovery and oily waste cleanup // Advanced Science. 2021. № 8 (15). P. 2004082.
14. Shah V., Panchal B., Gona C., Shah M., Prajapati M. A comprehensive study on applications of nanomaterials in petroleum upstream and downstream industry // Environmental Science and Pollution Research. 2024. № 31 (10). P. 14406 – 14423.
15. Hasan A.M., Kamal R.S., Farag R.K., Abdel-Raouf M.E. Petroleum sludge formation and its treatment methodologies: a review // Environmental Science and Pollution Research. 2024. № 31 (6). P. 8369 – 8386.
16. Ho M., El-Borgi S., Patil D., Song G. Inspection and monitoring systems subsea pipelines: A review paper. Structural Health Monitoring. 2020. № 19 (2). P. 606 – 645.
17. Khamees L.A., Abdul-Majeed G.H., Alhaleem A.A. A Review of Improving the Heavy Crude Oil Transportation Process Using Additives // Journal of Chemical & Petroleum Engineering. 2025. № 59 (2). P. 221 – 238.
18. Jia Q., Shen L., Zhou Z., Wang S., Liu L., Wang Y., Wang J. Flowability, carbon sequestration, and strength properties of carbonation-cured solid waste-based backfilling materials // Energy & Fuels. 2025. № 39 (37). P. 17990 – 18000.
19. Sutormin O.S., Goncharov A.S., Kratasyuk V.A., Petrova Y.Y., Bajbulatov R.Y., Yartsov A.E., Shpedt A.A. Effects of oil contamination on range of soil types in middle taiga of Western Siberia // Sustainability. 2024. № 16 (24). P. 11204 – 11209.
20. Pal D., Sen S. In-depth coverage of petroleum waste sources, characteristics, environmental impact, and sustainable remediation process. Impact of petroleum waste on environmental pollution and its sustainable management through circular economy. 2024. P. 1 – 38.
21. Adeoye A.O., Quadri R.O., Lawal O.S., Malomo D., Emojevu E.O., Omonije O.O., Saidu A.U. Advanced techniques in upgrading crude bio-oil to biofuel // Intelligent transportation system and advanced technology. Singapore: Springer Nature Singapore, 2024. P. 321 – 353.
22. Rahman W.U., Patel M., Kurian V., Kumar A. A comparative techno-economic assessment of fast pyrolysis, hydrothermal liquefaction, and intermediate pyrolysis of municipal solid waste for liquid transportation fuels production // Energy Conversion and Management. 2022. № 267. P. 115877 – 115892.
23. Zang Y., Liu G., Ji W., Li Y., Chen G. Resource utilization of expired progesterone medicines as flow improver for waxy crude oils // Journal of Environmental Management. 2024. № 349. P. 119524 – 1195538.
24. Huffman M., Hutchison V., Ranganathan S., Noll G., Baxter C., Hildebrand M., Wang Q. A comparative bibliometric study of the transport risk considerations of liquefied natural gas and liquefied petroleum gas // The Canadian Journal of Chemical Engineering. 2024. № 102 (6). P. 2019 – 2038.
25. Tanhaei H., Dehaghani A.H.S., Motlagh M.A.B. A Review of waste management approaches to maximise sustainable value of waste from the oil and gas industry. In The 2nd National and 1st International Conference on Environmental Challenges (Tarbiat Modares University). 2024. P. 34 – 45.
26. Hsu C. S., Robinson P. R. Crude Assay and Physical Properties. In Petroleum Science and Technology: Upstream/Midstream. Cham: Springer International Publishing. 2024. P. 25 – 45.
2. Taheri A., Shirmardi S. P. Applications of ionizing irradiation in oil industry: a review // Reviews in Chemical Engineering. 2025. Vol. 41. № 3. P. 241 – 268.
3. Alshahrani B., Korna A.H., Fares S.S., Ali A.H., Salman M. Assessing radiological hazards from NORM in oil and gas production residues: a comprehensive study // Radiation Effects and Defects in Solids. 2025. Vol. 180. № 9-10. P. 1307 – 1330.
4. Nasr A.S., Duraia E.M., Shafaa M.W., Ayoub H.A., Essa A.M. Evaluation and characterization of the radiological environmental impact of waste generated from the oil ash // Journal of Radioanalytical and Nuclear Chemistry. 2024. Vol. 333. № 11. P. 5867 – 5879.
5. Gogolinskiy K. V. Vinogradova A.A., Kopylavaet T.N. Study of physicochemical properties of polyethylene gas pipelines material with a prolonged service life // International Journal of Pressure Vessels and Piping. 2022. Vol. 200. P. 104825 – 104836.
6. Tanhaei H., Saeedi Dehaghani A. H. Improvement of the quality of heavy crude oil and reducing the concentration of asphaltene hydrocarbons using microwave radiation during acidizing // Scientific Reports. 2025. Vol. 15. № 1. P. 7434.
7. Morales-Hidalgo M., Povedano-Priego C., Martinez-Moreno M.F., Ruiz-Fresneda M.A., Lopez-Fernandez M., Jroundi F., Merroun M.L. Insights into the impact of physicochemical and microbiological parameters on the safety performance of deep geological repositories // Microorganisms. 2024. Vol. 12. № 5. P. 1025.
8. Joledo A.O., Orosun M.M., Ademola T. Radiological impact assessment of produced water from oilfield production facilities in the Niger Delta region // Nuclear Analysis. 2025. Vol. 4. №. 2. P. 100174.
9. Oliveira H., Pinheiro I., Ramos A., Venturini O., Mariano A., Santiago Y. Influence of physicochemical properties of oil sludge on syngas production for energy applications. Resources. 2024. Т. 14. № 1. P. 8 – 15.
10. Tang L., Wang T., Xu Y., He X., Yan A., Zhang Z., Li Y., Chen G. Research and application progress of crude oil demulsification technology // Processes. 2024. Vol. 12. № 10. P. 2292.
11. Guerrero-Martin C.A., Ortega-Ramírez A.T., Perilla Rodríguez P.A., Reyes López S.J., Guerrero-Martin L.E., Salinas-Silva R., Camacho-Galindo S. Analysis of environmental sustainability through a weighting matrix in the oil and gas industry // Sustainability. 2023. Vol. 15. № 11. P. 9063.
12. Elkatory M., Soliman E., Hassaan M., Ali R., Hafez E., Ibrahim H. S., Hashem A. Chemical mitigation technology for wax deposition in submarine oil pipeline systems // Egyptian Journal of Chemistry. 2021. № 64 (10). P. 5989 – 5997.
13. Lu Y., Zhu Y., Yang F., Xu Z., Liu Q. Advanced switchable molecules and materials for oil recovery and oily waste cleanup // Advanced Science. 2021. № 8 (15). P. 2004082.
14. Shah V., Panchal B., Gona C., Shah M., Prajapati M. A comprehensive study on applications of nanomaterials in petroleum upstream and downstream industry // Environmental Science and Pollution Research. 2024. № 31 (10). P. 14406 – 14423.
15. Hasan A.M., Kamal R.S., Farag R.K., Abdel-Raouf M.E. Petroleum sludge formation and its treatment methodologies: a review // Environmental Science and Pollution Research. 2024. № 31 (6). P. 8369 – 8386.
16. Ho M., El-Borgi S., Patil D., Song G. Inspection and monitoring systems subsea pipelines: A review paper. Structural Health Monitoring. 2020. № 19 (2). P. 606 – 645.
17. Khamees L.A., Abdul-Majeed G.H., Alhaleem A.A. A Review of Improving the Heavy Crude Oil Transportation Process Using Additives // Journal of Chemical & Petroleum Engineering. 2025. № 59 (2). P. 221 – 238.
18. Jia Q., Shen L., Zhou Z., Wang S., Liu L., Wang Y., Wang J. Flowability, carbon sequestration, and strength properties of carbonation-cured solid waste-based backfilling materials // Energy & Fuels. 2025. № 39 (37). P. 17990 – 18000.
19. Sutormin O.S., Goncharov A.S., Kratasyuk V.A., Petrova Y.Y., Bajbulatov R.Y., Yartsov A.E., Shpedt A.A. Effects of oil contamination on range of soil types in middle taiga of Western Siberia // Sustainability. 2024. № 16 (24). P. 11204 – 11209.
20. Pal D., Sen S. In-depth coverage of petroleum waste sources, characteristics, environmental impact, and sustainable remediation process. Impact of petroleum waste on environmental pollution and its sustainable management through circular economy. 2024. P. 1 – 38.
21. Adeoye A.O., Quadri R.O., Lawal O.S., Malomo D., Emojevu E.O., Omonije O.O., Saidu A.U. Advanced techniques in upgrading crude bio-oil to biofuel // Intelligent transportation system and advanced technology. Singapore: Springer Nature Singapore, 2024. P. 321 – 353.
22. Rahman W.U., Patel M., Kurian V., Kumar A. A comparative techno-economic assessment of fast pyrolysis, hydrothermal liquefaction, and intermediate pyrolysis of municipal solid waste for liquid transportation fuels production // Energy Conversion and Management. 2022. № 267. P. 115877 – 115892.
23. Zang Y., Liu G., Ji W., Li Y., Chen G. Resource utilization of expired progesterone medicines as flow improver for waxy crude oils // Journal of Environmental Management. 2024. № 349. P. 119524 – 1195538.
24. Huffman M., Hutchison V., Ranganathan S., Noll G., Baxter C., Hildebrand M., Wang Q. A comparative bibliometric study of the transport risk considerations of liquefied natural gas and liquefied petroleum gas // The Canadian Journal of Chemical Engineering. 2024. № 102 (6). P. 2019 – 2038.
25. Tanhaei H., Dehaghani A.H.S., Motlagh M.A.B. A Review of waste management approaches to maximise sustainable value of waste from the oil and gas industry. In The 2nd National and 1st International Conference on Environmental Challenges (Tarbiat Modares University). 2024. P. 34 – 45.
26. Hsu C. S., Robinson P. R. Crude Assay and Physical Properties. In Petroleum Science and Technology: Upstream/Midstream. Cham: Springer International Publishing. 2024. P. 25 – 45.
Понякин М.А. Исследование влияния ионизирующих излучений на физико-химические свойства твёрдых отходов транспортировки нефти по трубопроводам // Chemical Bulletin. 2026. Том 9. № 2. 1. https://doi.org/10.58224/2619-0575-2026-9-2-1