Keywords: thermogravimetric analysis

A study of the effect of ionizing radiation on the physicochemical properties of solid waste from oil pipeline transportation

https://doi.org/10.58224/2619-0575-2026-9-2-1
Abstract
The aim of the study was to experimentally investigate the effect of gamma irradiation in the absorbed dose range of 25-200 kGy on the physicochemical properties of solid waste from oil pipeline transportation. The object of the study was asphaltene-resin-paraffin deposits collected during the cleaning of a main oil pipeline. The following tasks were solved during the work: quantitative determination of changes in the group hydrocarbon composition (oils, paraffins, resins, asphaltenes) by adsorption chromatography; analysis of molecular weight distribution by gel permeation chromatography; assessment of rheological characteristics (melting point, pour point, relative viscosity) and thermal stability by thermogravimetric analysis. It was found that at a dose of 200 kGy, the paraffin content decreases by 1.65 times, while the asphaltene content increases by 1.8 times. The system's polydispersity increases from 6.56 to 10.72, the relative viscosity at 80°C more than doubles, and the coke residue increases from 3.5% to 8.2% by weight. The practical significance of these results lies in substantiating the possibility of using radiation-modified waste as a component of bitumen compositions with increased heat resistance or as a raw material for producing carbon materials. The data obtained can be used in the development of technologies for the disposal of oil waste using ionizing radiation.
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Application of thermal methods for the analysis of organic matter content in urbanozems

https://doi.org/10.58224/2619-0575-2024-7-1-32-40
Abstract
Objectives: the purpose of the study is to determine the content of organic matter in anthropogenic soils using thermal analysis methods.
Methods. Physico-chemical methods of soil sample analysis were used, the actual acidity, ash content and or-ganic matter were determined according to GOST 26213-2021 and by thermogravimetric analysis.
Results. It is shown that the content of organic substances in soils by thermogravimetry and according to GOST 26213-2021 differ by no more than 15.4%, which, in particular, may be due to the decomposition of inorganic sub-stances during prolonged exposure at a temperature of 525 ° C according to the GOST method. Nevertheless, the thermogravimetry method provides information about the temperatures at which the maximum decomposition rate is observed.
Conclusions. It has been established that the methods of thermogravimetry and according to GOST 26213-2021 give different results of the content of organic carbon in the soil due to different temperatures of maximum decom-position of humic acids. The higher the maximum decomposition temperature, the less organic substances decom-pose when studying soils by thermogravimetry.
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