4-12 p.
Nowadays, the popularity of vanadium flow batteries is rapidly growing in the world due to higher stability during long-term operation and low costs when creating systems with long battery life. At the same time, research aimed at developing methods to increase the electrocatalytic activity of carbon felt materials in relation to vanadium ions has been largely developed to increase the specific power of flow cells, which are an integral part of vanadium flow batteries. One of the approaches to the modification of these materials is plasma treatment. In this work, two-stage plasma treatment of carbon felt was carried out, first in the medium of one gas, and then in the medium of another gas. Oxygen and nitrogen are selected as the gas. It has been shown that regardless of the order in which plasma treatment is performed, there is a similar trend in the value of the potential difference between the peak of oxidation and the peak of reduction, first it increases in the first stage, and then decreases in the second stage. However, nitrogen treatment at the second stage tends to decrease the potential difference more rapidly (almost 2 times), which we observe in this work.
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2. Sun B., Skyllas-Kazacos M. Modification of graphite electrode materials for vanadium redox flow battery application-I. thermal treatment. Electrochemical Acta. 1992. Vol. 37. P. 1253 – 1260.
3. David O. Opar, Rosalynn Nankya, Jihye Lee, Hyun Jung Three-dimensional mesoporous graphene-modified carbon felt for high-performance vanadium redox flow batteries. Electrochimica Acta. 2020. Vol. 330. P. 1 – 14.
4. Jian-Zhang Chen, Wei-Yang Liao, Wen-Yen Hsieh, Cheng-Che Hsu, Yong-Song Chen All-vanadium redox flow batteries with graphite felt electrodes treated by atmospheric pressure plasma jets. Journal of Power Sources Vol. 15. January 2015. Vol. 274. P. 894 – 898.
5. Arunkumar M., Amit Paul, Importance of Electrode Preparation Methodologies in Supercapacitor Applica-tions. ACS Omega. 2017. Vol. 2. P. 8039 – 8050.
6. Wei G., Liu J., Zhao H., Yan C. Electrospun carbon nanofibres as electrode materials toward VO2+/VO2+ redox couple for vanadium flow battery. J. Power Sources. 2013. Vol. 241. P. 709 – 717.
7. Langner J., Bruns M., Dixon D., Nefedov A., Wo¨ll C., F. Scheiba, Ehrenberg H., Roth C., Melke J. Surface properties and graphitization of polyacrylonitrile based fiber electrodes affecting the negative half-cell reaction in vanadium redox flow batteries. J. Power Sources. 2016. Vol. 321. P. 210 – 218.
8. Sun B., Skyllas-Kazacos M. Chemical modification of graphite electrode materials for vanadium redox flow battery application part II. Acid treatments. Electrochim. 1992. Acta 37. P. 2459 – 2465.
9. L. Eifert Z., Jusys R.J., Behm R. Zeis Side reactions and stability of pre-treated carbon felt electrodes for va-nadium redox flow batteries: A DEMS study. Carbon. 2020. No. 158. P. 580 – 587.
10. Shao Y., Wang X., Engelhard M., Wang C., Dai S., Liu J., Yang Z., Lin Y. Nitrogen-doped mesopo-rous carbon for energy storage in vanadium redox flow batteries. J. Power Sources. 2010. Vol. 195. P. 4375 – 4379.
11. Sun J., Zeng L., Jiang H.R., Chao C.Y.H., Zhao T.S. Formation of electrodes by self-assembling po-rous carbon fibers into bundles for vanadium redox flow batteries. Journal of Power Sources. 2018. Vol. 405. P. 106 – 113.
12. Interaction of vanadium species with a functionalized graphite electrode: A combined theoretical and exper-imental study for flow battery applications. Mohadeseh Meskinfam Langroudi, Christian Silvio Pomelli, Romano Giglioli, Cinzia Chiappe, Maida Aysla Costa de Oliveira , Barbara Mecheri, Silvia Licoccia, Alessandra D'Epifanio. Journal of Power Sources. 2019. Vol. 420. P. 134 – 142.
Voropay A.N., Osetrov E.S. Investigation of the effect of plasma treatment of carbon felt on its electrochemical properties. Chemical Bulletin. 2024. 7 (4). P. 4 – 12. https://doi.org/10.58224/2619-0575-2024-7-4-4-12