THE USAGE OF VEGETABLE SORBENT FOR REMOVING CONGO RED DYE FROM TEST SOLUTIONS

The research findings of sorption purification of test water environment, containing Congo red dye, by using this crop farming waste as a sorption material have indicated that the maximum sorption capacity of its biomass amounts to 0.37 mmol/g. The electronic microscopy data and the research findings of physical-chemical and sorp-tion properties of a new vegetable sorption material, obtained from sunflower (Heliánthus ánnuus) stalks, are presented. The processing of the data demonstrated that the obtained adsorption isotherm of Congo red belongs to Type V isotherms according to classification by Brunauer-Deming-Deming-Teller (BDDT) or to the S-type, according to Giles’ classification. With that, adsorption process is the most accurately described by the Freundlich model, and the process proceeds on the heterogeneous surface of the sorption material.
1. Kramarenko L.V. Obezzarazhivanie vody s ispol'zovaniem metoda preammonizacii na Kochetokskom vodoprovode g. Har'kova. Kommunal'noe hozyajstvo gorodov. 2007. № 74. S. 177 – 185.
2. Rizk S.E., Hamed M.M. Batch sorption of iron complex dye, naphthol green B, from wastewater on charcoal, kaolinite, and tafla. Desalination and Water Treatment. 2015. T. 56. №. 6. S. 1536 – 1546. doi: 10.1080/19443994.2014.954004
3. Bhatia D., Sharma N.R., Singh J., Kanwar R.S. Biological methods for textile dye removal from wastewater: A review. Critical Reviews in Environmental Science and Technology. 2017. T. 47. № 19. S. 1836 – 1876. doi: 10.1080/10643389.2017.1393263
4. Vafina A.R., SHajhiev I.G. Issledovanie sorbcii krasitelya «Anionnyj yarko-zelenyj» iz model'nyh rastvorov s ispol'zovaniem obolochek zeren yachmenya. Vestnik Kazanskogo tekhnologicheskogo universiteta. 2016. T. 19. № 3.
5. Batoeva A.A., Sizyh M.R., Aseev D.G. Kombinirovannye okislitel'nye tekhnologii dlya ochistki stochnyh vod krasil'no-otdelochnyh proizvodstv. Vestnik Irkutskogo gosudarstvennogo tekhnicheskogo universiteta. 2010. № 3 (43).
6. Gablenko M.V., Timasheva N.A., SHalbak A., SHon L.T. Ispol'zovanie elektrohimicheskogo rastvora anolit dlya ochistki stochnyh vod ot sinteticheskih krasitelej. Uspekhi v himii i himicheskoj tekhnologii. 2008. T. 22. № 13 (93).
7. Abu Ghalwa N.M., Zaggout F.R. Electrodegradation of methylene blue dye in water and wastewater using lead oxide/titanium modified electrode. Journal of Environmental Science and Health, Part A. 2006. Vol. 41. № 10. P. 2271 – 2282. doi: 10.1080/10934520600872888
8. Kasperchik V.P., YAskevich A.L., Bil'dyukevich A.V. Ochistka stochnyh vod ot krasitelej s ispol'zovaniem koagulyacionnyh i membrannyh metodov. Membrany i membrannye tekhnologii. 2012. T. 2. №. 2. S. 133.
9. Mella B., Barcellos B.S. D.C. da Silva, Costa D.E., Gutterres M. Treatment of leather dyeing wastewater with associated process of coagulation-flocculation/adsorption/ozonation. Ozone: Science & Engineering. 2018. Vol. 40. № 2. S. 133-140. doi: 10.1080/01919512.2017.1346464
10. Saenko V.M., Hvostovich T.N. Ochistka stochnyh vod, soderzhashchih krasiteli, metodom obratnogo osmosa. V sb. nauchn. trudov. Himiya i himicheskaya tekhnologiya v bytovom obsluzhivanii naseleniya. Pod red. VA Volkova. M.: CNIIbyt, 1983. S. 107 – 112.
11. Ellouze E., Souissi S., Jrad A., Amar R.B., Salah A.B. Performances of nanofiltration and reverse osmosis in textile industry waste water treatment. Desalination and Water Treatment. 2010. Vol. 22. № 1-3. P. 182 – 186. doi: 10.5004/dwt.2010.1432
12. Bharathi K.S., Ramesh S.T. Removal of dyes using agricultural waste as low-cost adsorbents: a review. Applied Water Science. 2013. Vol. 3. P. 773 – 790. https://doi.org/10.1007/s13201-013-0117-y
13. Rafatullah M., Sulaiman O., Hashim R., Ahmad A. Adsorption of methylene blue on low-cost adsor-bents: A review. Journal of Hazardous Materials. 2010. Vol. 177. P. 70 – 80. doi:10.1016/j.jhazmat.2009.12.047
14. Geetha K.S., Belagali S.L. Removal of heavy metals and dyes using low cost adsorbents from aqueous medium-, A review. IOSR Journal Of Environmental Science, Toxicology And Food Technology. 2013. Vol. 4. № 3. P. 56 – 68.
15. Mohammed M.A., Shitu A., Ibrahim A. Removal of Methylene Blue Using Low Cost Adsorbent: A Review. Research Journal of Chemical Sciences. 2014. Vol. 4 (1). P. 91 – 102.
16. Sulyman M., Namiesnik J., Gierak A. Low-cost adsorbents derived from agricultural by-products/wastes for enhancing contaminant uptakes from wastewater: A review. Polish Journal of Envi-ronmental Studies. 2017. Vol. 26. № 2. P. 479 – 510. DOI: 10.15244/pjoes/66769
17. https://ru.wikipedia.org/wiki/Kongo_krasnyj
18. Wekoye J.N., Wanyonyi W.C., Wangila P.T., TonuiKinetic M.K. and equilibrium studies of Congo red dye adsorption on cabbage waste powder. Environmental Chemistry and Ecotoxicology. 2020. Vol. 2. P. 24 – 31.
19. Mondal N.K., Kar S. Potentiality of banana peel for removal of Congo red dye from aqueous solu-tion: isotherm, kinetics and thermodynamics studies. Applied Water Science. 2018. Vol. 8. Article 157. P. 1 – 12. https://doi.org/10.1007/s13201-018-0811-x
20. Munagapati V.S., Yarramuthi V., Kim Y. et al. Removal of anionic dyes (Reactive Black 5 and Congo Red) from aqueous solutions using Banana Peel Powder as an adsorbent. Ecotoxicology and Envi-ronmental Safety. 2018. Vol. 148. P. 601 – 607. https://doi.org/10.1016/j.ecoenv.2017.10.075
21. Han R., Ding D., Xu Y.et al. Use of rice husk for the adsorption of congo red from aqueous solution in column mode. Bioresource Technology. 2008. Vol. 99. P. 2938 – 2946. doi:10.1016/j.biortech.2007.06.027
22. Liu X., Wang B., Jing G., Sun Y. Adsorption behaviors of methylene blue on sunflower stem pith. Water Science and Technology. 2019. Vol. 79. № 8. P. 1458 – 1466.
23. Ghasemi S.M., Asgharnia H.A., Karimyan K., Adabi S. Adsorption of Basic Blue3 (BB3) dye from aqueous solution by tartaric acid modified sunflower stem: Kinetics and Equilibrium studies. International Research Journal of Applied and Basic Sciences. 2015. Vol. 9. № 5. P. 686 – 694.
24. Gcnen F., Kcyl' E. Environmental application of Telon Blue AGLF adsorption on sunflower pulp: A response surface methodology approach and kinetic study. Journal of Chemistry. 2016. Article ID 9621523. 10 p. http://dx.doi.org/10.1155/2016/9621523
25. Montes-Alba E.J., Camargo-Vargas G.J., Agudelo-Valencia R.N., Djvora-Isiordia G.E. Adsorption study of Acid Red 114 and Basic Blue 3 on sunflower stalk. Journal of Water Resource and Protection. 2019. Vol. 11 P. 68 – 81.
26. Sverguzova S.V., Loktionova E.V. Ispol'zovanie steblej podsolnechnika v kachestve sorbcionnyh materialov dlya ochistki stochnyh vod. Materialy mezhdunarodnoj nauchno-prakticheskoj konferencii «Bezopasnost', zashchita i ohrana okruzhayushchej prirodnoj sredy: fundamental'nye i prikladnye issledovaniya». Belgorod, 2019. S. 109 – 114.
27. Galimova R.Z., SHajhiev I.G., Sverguzova S.V. Obrabotka rezul'tatov issledovaniya processov adsorbcii s ispol'zovaniem programmnogo obespecheniya Microsoft Excel. 2017. 60 s.