English
Русский 48-59 p.
In recent years, the attention of researchers has been attracted by industrial and agricultural waste, which can be used as sorption materials. A special group is made up of lignocellulose-containing components of woody biomass (leaves, bark, needles, fruits, etc.) and wood processing products (sawdust, shavings, chips, etc.). Advantages of using the latter as reagents for wastewater treatment include simple technique, small processing, good adsorption capacity, selective adsorption of heavy metal ions, low cost, free availability and easy regeneration. Trees foliage attracts attention аmong the components of the woody biomass, it has a large specific surface area and falls annually under the conditions of the Russian Federation, which facilitates its collection and use.
Nickel ions are one of the most toxic pollutants that enter water bodies with industrial wastewater. The infor-mation on the nickel compounds toxic effect on living organisms is briefly presented. In this work, we studied the sorption properties of chestnut fallen leaves (CFL) in relation to nickel ions. The sorption capacity maximum value of the thermally modified CFL at a temperature of 250° C (CFL250) is 1.3 mmol / g for nickel ions. By processing the obtained isotherm within the framework of the Langmuir, Freundlich, BET, Dubinin-Radushkevich sorption models, it was found that the adsorption process is most accurately described by the Langmuir model (R2 = 0.9912). The calculated Gibbs energy is equal to -7.86 kJ / mol, it indicates the occurrence of spontaneous physical adsorption of Ni2 + ions on the CFL250 surface.
Nickel ions are one of the most toxic pollutants that enter water bodies with industrial wastewater. The infor-mation on the nickel compounds toxic effect on living organisms is briefly presented. In this work, we studied the sorption properties of chestnut fallen leaves (CFL) in relation to nickel ions. The sorption capacity maximum value of the thermally modified CFL at a temperature of 250° C (CFL250) is 1.3 mmol / g for nickel ions. By processing the obtained isotherm within the framework of the Langmuir, Freundlich, BET, Dubinin-Radushkevich sorption models, it was found that the adsorption process is most accurately described by the Langmuir model (R2 = 0.9912). The calculated Gibbs energy is equal to -7.86 kJ / mol, it indicates the occurrence of spontaneous physical adsorption of Ni2 + ions on the CFL250 surface.
1. Jyotikusum A., Upendra K.P., Mahammed R. Removal of Heavy Metal Ions from Wastewater by Chemically Modified Agricultural Waste Material as Potential Adsorbent-AReview. International Journal of Current Engineer-ing and Technology. 2018. № 8 (3). P. 526 – 530.
2. Holleman A.F., Wiberg E. Water de Gruyter, Berlin.1985. 868 p.
3. Nikel' [Elektronnyj resurs]. URL: https://ru.wikipedia.org/wiki/ Nikel'
4. Filatova E.G. Izvestiya VUZov. Obzor tekhnologij ochistki stochnyh vod ot ionov tyazhelyh metallov, osno-vannyh na fiziko-himicheskih processah. Prikladnaya himiya i biotekhnologiya. 2015. № 2 (13). S. 97 – 109.
5. Bolisetty S., Peydayesh M., Mezzenga R. Sustainable technologies for water purification from heavy metals: review and analysis. Chemical Society Reviews. 2019. № 48. P. 463 – 487.
6. Azimi A., Azari A., Rezakazemi M., Ansarpour M. Removal of heavy metals from industrial wastewaters: a review. ChemBioEng Rev. 2017. № 4 (1). P. 37 – 59.
7. Carolin C.F., Kumar P.S., Saravanan A., Joshiba G.J., Naushad M. Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review. Journal of Environmental Chemical Engineering. 2017. № 5 (3). P. 2782 – 2799.
8. Joseph L., Jun B., Flora J.R.V., Park C.M., Yoon Y. Removal of heavy metals from water sources in the de-veloping world using low-cost materials: A review. Chemosphere. 2019. № 229. P. 142 – 159.
9. Malik D.S., Jain C.K., Yadav A.K. Removal of heavy metals from emerging cellulosic low-cost adsorbents: a review. Applied Water Science. 2017. № 7. P. 2113 – 2136.
10. Farhadi A., Ameri A., Tamjidi S. Application of Agricultural Wastes as a Low-cost Adsorbent for Removal of Heavy Metals and Dyes from Wastewater: A Review Study. Physical Chemistry Research. 2021. № 9 (2). P. 211 – 226.
11. Shaikhiev I.G., Kraysman N.V., Sverguzova S.V. Review of Almond (Prunus Dulcis) Shell Use to Remove Pollutants from Aquatic Environments. Biointerface Research in Applied Chemistry. 2021. № 11 (6). P. 14866 – 14880.
12. Shaikhiev I.G., Sverguzova S.V., Galimova R.Z., Grechina A.S. Using wastes of buckwheat processing as sorption materials for the removal of pollutants from aqueous media: a review. IOP Conf. Series: Materials Science and Engineering. 2020. Vol. 945. P. 012044.
13. Sverguzova S.V., Shaikhiev I.G., Fomina E.V., Galimova R.Z. Use of chestnut sheel (castánea) as adsorption material for removing pollutants from natural and sewage waters: a review. IOP Conf. Series: Materials Science and Engineering. 2020. Vol. 945. P. 012072.
14. Shajhiev I.G., Stepanova S.V., Sverguzova S.V. Udalenie ionov kobal'ta vysokih koncentracij iz model'nyh rastvorov s ispol'zovaniem ekstraktov iz othodov pererabotki pisum sativum. Vestnik BGTU im. V.G. SHuhova 2016. № 7. S. 159 – 166.
15. SHajhiev I.G., Sverguzova S.V., Grechina A.S., Shajhieva K.I. Ispol'zovanie othodov ot pererabotki bio-massy ovsa v kachestve sorbcionnyh materialov dlya udaleniya pollyutantov iz vodnyh sred (obzor literatury). Ekonomika stroitel'stva i prirodopol'zovaniya. 2018. № 2 (67). S. 51 – 60.
16. Denisova T.R., SHajhiev I.G. Ispol'zovanie komponentov listvennyh derev'ev srednej polo-sy rossii v kachestve sorbcionnyh materialov dlya udaleniya pollyutantov iz vodnyh sred. obzor literatury. Vestnik tekhnolog-icheskogo universiteta. 2017. № 20 (24). S. 145 – 158.
17. Shajhiev I.G. Ispol'zovanie komponentov derev'ev roda quercus v kachestve sorbcionnyh ma-terialov dlya udaleniya pollyutantov iz vody. obzor literatury. Vestnik tekhnologicheskogo univer-siteta. 2017. № 20 (5). S. 151 – 160.
18. Shajhiev I.G., Nguen T.K.T., Shajhieva K.I. Ispol'zovanie komponentov derev'ev roda acacia dlya udaleniya pollyutantov iz prirodnyh i stochnyh vod. 1. iony tyazhelyh metallov. Vestnik tekhno-logicheskogo universiteta. 2017. № 20 (3). S. 171 – 179.
19. Shajhiev I.G., Shajhieva K.I. Ispol'zovanie komponentov hvojnyh derev'ev dlya udaleniya pollyutantov iz vodnyh sred. 5. Kedrovye. Vestnik tekhnologicheskogo universiteta. 2016. № 19 (16). S. 177 – 179.
20. Shajhiev I.G., Shajhieva K.I. Ispol'zovanie komponentov hvojnyh derev'ev dlya udaleniya pollyutantov iz vodnyh sred. 6. Kiparisovye. Vestnik tekhnologicheskogo universiteta. 2016. № 19 (22).S. 162 – 167.
21. Alekseeva A., Fazullin D., Kharlyamov D., Mavrin G., Stepanova S., Shaikhiev I., Shaimardanova A. The use of leaves of different tree species as a sorption material for extraction of heavy metal ions from aqueous media. International Journal of Pharmacy & Technology. 2016. № 8 (2). P. 14375 – 14391.
22. Bhattacharyya K.G., Sarma J., Sarma A. Azadirachta indica leaf powder as a biosorbent for ni(ii) in aqueous medium. Journal of hazardous materials. 2009. № 165 (1-3). P. 271 – 278.
23. Zolgharnein J., Bagtash M., Feshki S., Zolgharnein P., Hammond D. Crossed mixture process design opti-mization and adsorption characterization of multi-metal (Cu(II), Zn(II) and Ni(II)) removal by modified Buxus sempervirens tree leaves. Journal of the Taiwan Institute of Chemical Engineers. 2017. № 78. P. 104 – 117.
24. Babalola B.M., Babalola A.O., Akintayo C.O., Lawal O.S., Abimbade S.F., Oseghe E.O., Akinola L.S., Ayanda O.S. Adsorption and desorption studies of Delonix regia pods and leaves: removal and recovery of Ni(II) and Cu(II) ions from aqueous solution. Drink. Water Eng. Sci. 2020. № 13. P. 15 – 27.
25. Svyatchenko A.V., Sapronova Zh.A., Sverguzova S.V., Porozhnyuk E.A., Lupandina N.S. Vestnik Opre-delenie optimal'nyh parametrov modifikacii cellyulozosoderzhashchego sorbcionnogo materiala (listovogo kashta-novogo opada). Kamchatskogo gosudarstvennogo tekhnologicheskogo universiteta. 2020. № 52. S. 40 – 49.
26. Sverguzova S.V., Sapronova Zh.A., Svyatchenko A.V., Otiti T. Adsorbciya veretennogo masla na-tivnym i termomodificirovannym listovym opadom kashtanov. Stroitel'nye materialy i izdeliya. 2018. № 1 (1). S. 4 – 11.
27. Sapronova Zh.A., Svyatchenko A.V. Sorbent na osnove list'ev kashtana dlya ochistki stochnyh vod ot nefte-produktov. Innovacionnye podhody v reshenii sovremennyh problem racional'nogo ispol'zovaniya prirodnyh resur-sov i ohrany okruzhayushchej sredy: Sbornik dokladov Mezhdunarodnoj nauchno-tekhnicheskoj konferencii. 2019. S. 4 – 6.
28. Svyatchenko A.V., Chetverikov A.V., Sapronova Zh.A., Shajhiev I.G. Issledovanie processa ochistki maslosoderzhashchej emul'sii s pomoshch'yu metoda planirovaniya eksperimenta. Chemical Bulletin. 2018. № 4. T. 1. S. 19 – 30.
29. Sverguzova S.V., Sapronova Zh.A., Svyatchenko A.V. O vozmozhnosti primeneniya listovogo opada kashtanov dlya ochistki vodnyh sistem ot ionov medi. Innovacionnye puti resheniya aktual'nyh problem pri-rodopol'zovaniya i zashchity okruzhayushchej sredy: Sbornik dokladov Mezhdunarodnoj nauchno-tekhnicheskoj konferencii. 2018. S. 212 – 216.
30. RD 52.24.494-95 Metodicheskie ukazaniya. Metodika vypolneniya izmerenij massovoj koncen-tracii nikelya v poverhnostnyh vodah sushi fotometricheskim metodom s dimetilglioksimom. Rosgidromet, 2006.
31. Galimova R.3., Shajhiev I.G., Sverguzova S.V. Obrabotka rezul'tatov issledovaniya processov adsorbcii s ispol'zovaniem programmnogo obespecheniya Microsoft Excel: praktikum. BGTU, Kazan', 2017. 60 s.
32. Galimova R.Z., Shajhiev I.G., Kamalova N.A., Sverguzova S.V. Vliyanie rH sredy na protekanie processov adsorbcii ionov medi, nikelya i cinka igolkami listvennicy sibirskoj (larix sibirica). Sorbcionnye i hromatografich-eskie processy. 2020. № 20 (3). S. 400 – 407.
33. Galimova R.Z., Shajhiev I.G., Almazova G.A. Izuchenie termodinamiki sorbcii fenola na ot-hodah valyal'no-vojlochnogo proizvodstva (ugare). Vestnik tekhnologicheskogo universiteta. 2016. № 19 (14). S. 169 – 171.
2. Holleman A.F., Wiberg E. Water de Gruyter, Berlin.1985. 868 p.
3. Nikel' [Elektronnyj resurs]. URL: https://ru.wikipedia.org/wiki/ Nikel'
4. Filatova E.G. Izvestiya VUZov. Obzor tekhnologij ochistki stochnyh vod ot ionov tyazhelyh metallov, osno-vannyh na fiziko-himicheskih processah. Prikladnaya himiya i biotekhnologiya. 2015. № 2 (13). S. 97 – 109.
5. Bolisetty S., Peydayesh M., Mezzenga R. Sustainable technologies for water purification from heavy metals: review and analysis. Chemical Society Reviews. 2019. № 48. P. 463 – 487.
6. Azimi A., Azari A., Rezakazemi M., Ansarpour M. Removal of heavy metals from industrial wastewaters: a review. ChemBioEng Rev. 2017. № 4 (1). P. 37 – 59.
7. Carolin C.F., Kumar P.S., Saravanan A., Joshiba G.J., Naushad M. Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review. Journal of Environmental Chemical Engineering. 2017. № 5 (3). P. 2782 – 2799.
8. Joseph L., Jun B., Flora J.R.V., Park C.M., Yoon Y. Removal of heavy metals from water sources in the de-veloping world using low-cost materials: A review. Chemosphere. 2019. № 229. P. 142 – 159.
9. Malik D.S., Jain C.K., Yadav A.K. Removal of heavy metals from emerging cellulosic low-cost adsorbents: a review. Applied Water Science. 2017. № 7. P. 2113 – 2136.
10. Farhadi A., Ameri A., Tamjidi S. Application of Agricultural Wastes as a Low-cost Adsorbent for Removal of Heavy Metals and Dyes from Wastewater: A Review Study. Physical Chemistry Research. 2021. № 9 (2). P. 211 – 226.
11. Shaikhiev I.G., Kraysman N.V., Sverguzova S.V. Review of Almond (Prunus Dulcis) Shell Use to Remove Pollutants from Aquatic Environments. Biointerface Research in Applied Chemistry. 2021. № 11 (6). P. 14866 – 14880.
12. Shaikhiev I.G., Sverguzova S.V., Galimova R.Z., Grechina A.S. Using wastes of buckwheat processing as sorption materials for the removal of pollutants from aqueous media: a review. IOP Conf. Series: Materials Science and Engineering. 2020. Vol. 945. P. 012044.
13. Sverguzova S.V., Shaikhiev I.G., Fomina E.V., Galimova R.Z. Use of chestnut sheel (castánea) as adsorption material for removing pollutants from natural and sewage waters: a review. IOP Conf. Series: Materials Science and Engineering. 2020. Vol. 945. P. 012072.
14. Shajhiev I.G., Stepanova S.V., Sverguzova S.V. Udalenie ionov kobal'ta vysokih koncentracij iz model'nyh rastvorov s ispol'zovaniem ekstraktov iz othodov pererabotki pisum sativum. Vestnik BGTU im. V.G. SHuhova 2016. № 7. S. 159 – 166.
15. SHajhiev I.G., Sverguzova S.V., Grechina A.S., Shajhieva K.I. Ispol'zovanie othodov ot pererabotki bio-massy ovsa v kachestve sorbcionnyh materialov dlya udaleniya pollyutantov iz vodnyh sred (obzor literatury). Ekonomika stroitel'stva i prirodopol'zovaniya. 2018. № 2 (67). S. 51 – 60.
16. Denisova T.R., SHajhiev I.G. Ispol'zovanie komponentov listvennyh derev'ev srednej polo-sy rossii v kachestve sorbcionnyh materialov dlya udaleniya pollyutantov iz vodnyh sred. obzor literatury. Vestnik tekhnolog-icheskogo universiteta. 2017. № 20 (24). S. 145 – 158.
17. Shajhiev I.G. Ispol'zovanie komponentov derev'ev roda quercus v kachestve sorbcionnyh ma-terialov dlya udaleniya pollyutantov iz vody. obzor literatury. Vestnik tekhnologicheskogo univer-siteta. 2017. № 20 (5). S. 151 – 160.
18. Shajhiev I.G., Nguen T.K.T., Shajhieva K.I. Ispol'zovanie komponentov derev'ev roda acacia dlya udaleniya pollyutantov iz prirodnyh i stochnyh vod. 1. iony tyazhelyh metallov. Vestnik tekhno-logicheskogo universiteta. 2017. № 20 (3). S. 171 – 179.
19. Shajhiev I.G., Shajhieva K.I. Ispol'zovanie komponentov hvojnyh derev'ev dlya udaleniya pollyutantov iz vodnyh sred. 5. Kedrovye. Vestnik tekhnologicheskogo universiteta. 2016. № 19 (16). S. 177 – 179.
20. Shajhiev I.G., Shajhieva K.I. Ispol'zovanie komponentov hvojnyh derev'ev dlya udaleniya pollyutantov iz vodnyh sred. 6. Kiparisovye. Vestnik tekhnologicheskogo universiteta. 2016. № 19 (22).S. 162 – 167.
21. Alekseeva A., Fazullin D., Kharlyamov D., Mavrin G., Stepanova S., Shaikhiev I., Shaimardanova A. The use of leaves of different tree species as a sorption material for extraction of heavy metal ions from aqueous media. International Journal of Pharmacy & Technology. 2016. № 8 (2). P. 14375 – 14391.
22. Bhattacharyya K.G., Sarma J., Sarma A. Azadirachta indica leaf powder as a biosorbent for ni(ii) in aqueous medium. Journal of hazardous materials. 2009. № 165 (1-3). P. 271 – 278.
23. Zolgharnein J., Bagtash M., Feshki S., Zolgharnein P., Hammond D. Crossed mixture process design opti-mization and adsorption characterization of multi-metal (Cu(II), Zn(II) and Ni(II)) removal by modified Buxus sempervirens tree leaves. Journal of the Taiwan Institute of Chemical Engineers. 2017. № 78. P. 104 – 117.
24. Babalola B.M., Babalola A.O., Akintayo C.O., Lawal O.S., Abimbade S.F., Oseghe E.O., Akinola L.S., Ayanda O.S. Adsorption and desorption studies of Delonix regia pods and leaves: removal and recovery of Ni(II) and Cu(II) ions from aqueous solution. Drink. Water Eng. Sci. 2020. № 13. P. 15 – 27.
25. Svyatchenko A.V., Sapronova Zh.A., Sverguzova S.V., Porozhnyuk E.A., Lupandina N.S. Vestnik Opre-delenie optimal'nyh parametrov modifikacii cellyulozosoderzhashchego sorbcionnogo materiala (listovogo kashta-novogo opada). Kamchatskogo gosudarstvennogo tekhnologicheskogo universiteta. 2020. № 52. S. 40 – 49.
26. Sverguzova S.V., Sapronova Zh.A., Svyatchenko A.V., Otiti T. Adsorbciya veretennogo masla na-tivnym i termomodificirovannym listovym opadom kashtanov. Stroitel'nye materialy i izdeliya. 2018. № 1 (1). S. 4 – 11.
27. Sapronova Zh.A., Svyatchenko A.V. Sorbent na osnove list'ev kashtana dlya ochistki stochnyh vod ot nefte-produktov. Innovacionnye podhody v reshenii sovremennyh problem racional'nogo ispol'zovaniya prirodnyh resur-sov i ohrany okruzhayushchej sredy: Sbornik dokladov Mezhdunarodnoj nauchno-tekhnicheskoj konferencii. 2019. S. 4 – 6.
28. Svyatchenko A.V., Chetverikov A.V., Sapronova Zh.A., Shajhiev I.G. Issledovanie processa ochistki maslosoderzhashchej emul'sii s pomoshch'yu metoda planirovaniya eksperimenta. Chemical Bulletin. 2018. № 4. T. 1. S. 19 – 30.
29. Sverguzova S.V., Sapronova Zh.A., Svyatchenko A.V. O vozmozhnosti primeneniya listovogo opada kashtanov dlya ochistki vodnyh sistem ot ionov medi. Innovacionnye puti resheniya aktual'nyh problem pri-rodopol'zovaniya i zashchity okruzhayushchej sredy: Sbornik dokladov Mezhdunarodnoj nauchno-tekhnicheskoj konferencii. 2018. S. 212 – 216.
30. RD 52.24.494-95 Metodicheskie ukazaniya. Metodika vypolneniya izmerenij massovoj koncen-tracii nikelya v poverhnostnyh vodah sushi fotometricheskim metodom s dimetilglioksimom. Rosgidromet, 2006.
31. Galimova R.3., Shajhiev I.G., Sverguzova S.V. Obrabotka rezul'tatov issledovaniya processov adsorbcii s ispol'zovaniem programmnogo obespecheniya Microsoft Excel: praktikum. BGTU, Kazan', 2017. 60 s.
32. Galimova R.Z., Shajhiev I.G., Kamalova N.A., Sverguzova S.V. Vliyanie rH sredy na protekanie processov adsorbcii ionov medi, nikelya i cinka igolkami listvennicy sibirskoj (larix sibirica). Sorbcionnye i hromatografich-eskie processy. 2020. № 20 (3). S. 400 – 407.
33. Galimova R.Z., Shajhiev I.G., Almazova G.A. Izuchenie termodinamiki sorbcii fenola na ot-hodah valyal'no-vojlochnogo proizvodstva (ugare). Vestnik tekhnologicheskogo universiteta. 2016. № 19 (14). S. 169 – 171.