English
Русский 16-26 p.
New halogen-containing oligoesterketones have been synthesized by high-temperature polycondensation in an aprotic dipolar solvent in an inert gas atmosphere, and methods have been developed for producing new monomers and oligomers suitable for the production of aromatic polyesters based on halogen-containing monomers with the replacement of the traditional 4,4-difluorobenzophenone with a chlorine-containing monomer. The substantiation of the choice of the research task, the technical and economic aspects of the problem and the ways of its solution are presented. The task of synthesizing monomers and oligomers for the subsequent polymerization of aromatic polyesters is due to the importance of ensuring the relationship of the properties of the synthesized polymer from the list and characteristics of the base materials used. Thus, methods for obtaining monomers and oligomers based on them have been developed, correlation dependences of the properties of the obtained materials on the composition and quantity of fillers used have been investigated. Nucleophilic substitution reactions for the production of oligomers are described. The structures of the obtained monomers and oligomers are determined and possible areas of their application are established, data on the study of the properties of the obtained materials by IR spectroscopy, elemental and X-ray diffraction analysis, TGA, DSC, etc. are presented. The practical significance and applicability of the obtained materials and products for various purposes is proposed, taking into account the requirements for materials with high heat resistance, physico-mechanical, operational characteristics.
1. Peksimov O.E., Balabanova V.A., Dinzburg I.L., Kazakov S.I. Termostojkie konstrukcionnye termoplasty – polisul'fony marki PSF-190, UDEL P-1700. Teplofizicheskie, dielektricheskie, fiziko-mekhanicheskie svojstva v shirokom diapazone temperatur i skorostej ispytanij. Plasticheskie massy. 2013. № 11. S. 20 – 21.
2. Kozlova E.E., Borodulin A.S., CHukov N.A., Vasil'eva S.V., Bedanokov DDT i ego proizvodnye v kachestve perspektivnyh monomerov dlya polucheniya poliefirketonov. «Izvestiya Kabardino-Balkarskogo gosudarstvennogo universiteta». 2020. T. Х. № 2. S. 57 – 61.
3. Zenitova L.A., SHtejnberg E.M. Polisul'fon kak funkcional'nyj polimernyj material i ego proizvodstvo. Mezhdunarodnyj nauchno-issledovatel'skij zhurnal. 2012. № 6 (6). S. 23 – 28.
4. Kharaev A.M., Shaov A.Kh., Bazheva R.Ch. The synthesis and stabilization of polymers: Monograph. Saar-brücken, LAMBERT Academic Publishing, 2013, 300 p.
5. Bazheva R.CH., Haraev A.M., Inarkieva Z.I., Beslaneeva Z.L. Sopolikarbonaty, soderzhashchie di-hloretilenovye gruppy v osnovnoj cepi. Plasticheskie massy. 2017. № 3-4. S. 32 – 35.
6. Haraev A.M., Bazheva R.CH., Lukozhev R.V., Inarkieva Z.I., Barokova E.B. Sintez i svojstva poli-arilenefirketonov na osnove nekotoryh proizvodnyh hloralya. Plasticheskie massy. 2014. № 5-6. S. 24 – 28.
7. Mikitaev A.K., Rusanov A.L., Koumykov R.M. The novel polynaphthylimides of improved solubility on the basis of derivatives from chloral and dichlordiphenyltrichlorethane. Characterization and Development of Novel Materials Research Compendium. 2013. S. 186 – 192.
8. Kumykov R.M., Vologirov A.K. Novye aromaticheskie dinitroproizvodnye hloralya kak monomery dlya sin-teza poliefirov i poligeteroarilenov. Izvestiya vysshih uchebnyh zavedenij. Seriya: Himiya i himicheskaya tekhnologiya. 2018. T. 61. № 2. S. 4 – 14.
9. CHukov N.A., Borodulin A.S., Kerefov T.O., Kozlova E.E., Hashkhozheva R.R Kondensacionnye monomery i poliefirketony na ih osnove. «Izvestiya Kabardino-Balkarskogo gosudarstvennogo universiteta». 2020. T. X. № 2. S. 51 ؘ– 55
10. Oranova T.I.Issledovanie reakcij ciklizacii poliamidokislot i poluchenie modificirovannyh imidsoderzhash-chih polimerov: dis. … na soisk. step. dokt. himich. nauk, 1998 g.
11. Kharaev A.M., Oshroeva R.Z., Zaikov G.E. Halogen containing simple and complicated block copol-yethers. Chemical and Biochemical Physics. A Systematic Approach to Experiments, Evaluation, and Modeling. Apple Academic Press. Canada. 2016. P. 3 – 13.
12. Barokova E.B., Haraev A.M., Bazheva R.C., Haraeva R.A. Oligosulfons on the basis of 1,1-dichlor-2,2- di(4-oxyphenyl)ethylene and 4,4'-dichlorodiphenylsulfone obtained by high temperature polycondensation. Hand-book of Condensed Phase Chemistry. 2010. S. 233 – 236.
13. Kharayev A.M., Mikitaev A.K., Zaikov G.E., Bazheva R.C. The Synthesis and Properties of Unsaturated Halogen-Containing Poly (Arylene Ether Ketone)S. Monomers, Oligomers, Polymers, Composites and Nanocom-posites Research: Synthesis, Properties and Applications. Ed. by Richard A. Pethrick, G.E. Zaikov, J. PIelichowski. NY: Nova Science Publishers Inc. 2009. P. 103 – 114.
2. Kozlova E.E., Borodulin A.S., CHukov N.A., Vasil'eva S.V., Bedanokov DDT i ego proizvodnye v kachestve perspektivnyh monomerov dlya polucheniya poliefirketonov. «Izvestiya Kabardino-Balkarskogo gosudarstvennogo universiteta». 2020. T. Х. № 2. S. 57 – 61.
3. Zenitova L.A., SHtejnberg E.M. Polisul'fon kak funkcional'nyj polimernyj material i ego proizvodstvo. Mezhdunarodnyj nauchno-issledovatel'skij zhurnal. 2012. № 6 (6). S. 23 – 28.
4. Kharaev A.M., Shaov A.Kh., Bazheva R.Ch. The synthesis and stabilization of polymers: Monograph. Saar-brücken, LAMBERT Academic Publishing, 2013, 300 p.
5. Bazheva R.CH., Haraev A.M., Inarkieva Z.I., Beslaneeva Z.L. Sopolikarbonaty, soderzhashchie di-hloretilenovye gruppy v osnovnoj cepi. Plasticheskie massy. 2017. № 3-4. S. 32 – 35.
6. Haraev A.M., Bazheva R.CH., Lukozhev R.V., Inarkieva Z.I., Barokova E.B. Sintez i svojstva poli-arilenefirketonov na osnove nekotoryh proizvodnyh hloralya. Plasticheskie massy. 2014. № 5-6. S. 24 – 28.
7. Mikitaev A.K., Rusanov A.L., Koumykov R.M. The novel polynaphthylimides of improved solubility on the basis of derivatives from chloral and dichlordiphenyltrichlorethane. Characterization and Development of Novel Materials Research Compendium. 2013. S. 186 – 192.
8. Kumykov R.M., Vologirov A.K. Novye aromaticheskie dinitroproizvodnye hloralya kak monomery dlya sin-teza poliefirov i poligeteroarilenov. Izvestiya vysshih uchebnyh zavedenij. Seriya: Himiya i himicheskaya tekhnologiya. 2018. T. 61. № 2. S. 4 – 14.
9. CHukov N.A., Borodulin A.S., Kerefov T.O., Kozlova E.E., Hashkhozheva R.R Kondensacionnye monomery i poliefirketony na ih osnove. «Izvestiya Kabardino-Balkarskogo gosudarstvennogo universiteta». 2020. T. X. № 2. S. 51 ؘ– 55
10. Oranova T.I.Issledovanie reakcij ciklizacii poliamidokislot i poluchenie modificirovannyh imidsoderzhash-chih polimerov: dis. … na soisk. step. dokt. himich. nauk, 1998 g.
11. Kharaev A.M., Oshroeva R.Z., Zaikov G.E. Halogen containing simple and complicated block copol-yethers. Chemical and Biochemical Physics. A Systematic Approach to Experiments, Evaluation, and Modeling. Apple Academic Press. Canada. 2016. P. 3 – 13.
12. Barokova E.B., Haraev A.M., Bazheva R.C., Haraeva R.A. Oligosulfons on the basis of 1,1-dichlor-2,2- di(4-oxyphenyl)ethylene and 4,4'-dichlorodiphenylsulfone obtained by high temperature polycondensation. Hand-book of Condensed Phase Chemistry. 2010. S. 233 – 236.
13. Kharayev A.M., Mikitaev A.K., Zaikov G.E., Bazheva R.C. The Synthesis and Properties of Unsaturated Halogen-Containing Poly (Arylene Ether Ketone)S. Monomers, Oligomers, Polymers, Composites and Nanocom-posites Research: Synthesis, Properties and Applications. Ed. by Richard A. Pethrick, G.E. Zaikov, J. PIelichowski. NY: Nova Science Publishers Inc. 2009. P. 103 – 114.