English
Русский 19-28 p.
Electrode materials based on platinum metal nanoparticles are widely used to create alternative energy sources with high specific characteristics. Industrial carbon-containing carriers and perfluorinated proton exchange membranes of the Nafion type are used as matrices for the fuel cell electrodes formation. In this work, new effective polymer-carbon catalysts modified with platinum nanoparticles have been synthesized. Physicochemical and functional characteristics of nanocomposites have been studied by electron microscopy, X-ray phase analysis, small-angle X-ray scattering and cyclic voltammetry. Increased catalytic activity and stability of the formed electrodes in hydrogen-oxygen fuel cells had been found. The test results of hydrogen-air fuel cells in model operating conditions had been obtained. The current density maximum parameters of the membrane-electrode assemblies had been found for nanocomposites formed on multi-walled carbon nanotubes with a solubilization coefficient of ω equal to 1.5 and a platinum content of 0.35 mg/cm2. The creation of new membrane-electrode assemblies helps to reduce the cost of chemical current sources, as well as increase their energy efficiency.
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2. Möst D., Schreiber S., Herbst A., Jakob M., Martino A., Poganietz W.-R. The Future European Energy System: Renewable Energy, Flexibility Options And Technological Progress. Springer, 2021. 321 p.
3. Khellaf A. Advances in Renewable Hydrogen and Other Sustainable Energy Carriers. Springer Singapore, 2021. 517 p.
4. Zhang J., Shen S. Low Platinum Fuel Cell Technologies. Springer Berlin Heidelberg, 2021. 223 p.
5. Xing Y. Modeling and Control Strategies for a Fuel Cell System Springer, 2023. 177 p.
6. Hwang C.-K., Lee K.A., Lee J., Kim Y., Ahn H., Hwang W., Ju B.-K., Kim J.Y., Yeo S.Y., Choi J., Sung Y.-E., Kim I.-D., Yoon K.R. Perpendicularly stacked array of PTFE nanofibers as a reinforcement for highly durable composite membrane in proton exchange membrane fuel cells. Nano Energy. 2022. V. 101. P. 107581.
7. Liu L., Li X., Liu Z., Zhang S., Qian L., Chen Z., Li J., Fang P., He C. High-performance fuel cells using Nafion composite membranes with alignment of sulfonated graphene oxides induced by a strong magnetic field. Journal of Membrane Science. 2022. V. 653. P. 120516.
8. Gómez M.A., Navarro A.J., Giner-Casares J.J., Cano M., Fernández-Romero A.J., López-Cascales J.J. Electrodes based on nafion and epoxy-graphene composites for improving the performance and durability of open cathode fuel cells, prepared by electrospray deposition. International Journal of Hydrogen Energy. 2022. V. 47. № 29. P. 13980 – 13989.
9. Liu S., Yuan S., Liang Y., Li H., Xu Z., Xu Q., Yin J., Shen S., Yan X., Zhang J. Engineering the catalyst layers towards enhanced local oxygen transport of Low-Pt proton exchange membrane fuel cells: Materials, designs, and methods. International Journal of Hydrogen Energy. 2023. V. 48. № 11. R. 4389 – 4417.
10. Jashtulov N.A., Lebedeva M.V., Ragutkin A.V., Zajcev N.K. Jelektrodnye materialy na osnove poristogo kremnija s nanochasticami platiny dlja himicheskih istochnikov toka. Zhurnal prikladnoj himii. 2018. T. 91. № 2. S. 232 – 237.
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12. Lebedeva M.V., Antropov A.P., Ragutkin A.V., Jashtulov N.A. Platinovye nanojelektrokatalizatory dlja vodorodno-vozdushnyh istochnikov jenergii. Computational Nanotechnology. 2020. T. 7. № 1. S. 26 – 29.
13. Serov A., Shum A.D., Xiao X., De Andrade V., Artyushkova K., Zenyuk I.V. Atanassov P. Nano-structured platinum group metal-free catalysts and their integration in fuel cell electrode architectures. Applied Catalysis B: Environmental. 2018. V. 237. P. 1139 – 1147.
14. Battirola L.C., Schneider J.F., Torriani I.C.L., Tremiliosi-Filho G. Improvement on direct ethanol fuel cell performance by using doped-Nafion 117 membranes with Pt and Pt-Ru nanoparticles. Int. J. Hydr. Energy. 2013. V. 38. № 27. P. 12060 – 12068.
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17. Lebedeva M.V., Svitov V.I., Kaplan I.M. Fiziko-himicheskie osobennosti formirovanija palladievyh nanokatalizatorov na dvuhkomponentnyh membranah dlja toplivnyh jelementov. Chemical Bulletin. 2021. T. 4. № 2. S. 58 – 66.
Lebedeva M.V., Krapivko A.L., Dulina O.A., Lenskyi M.S., Yashtulov N.A. Energy-efficient nanocomposite membrane-electrode blocks for chemical current sources. Chemical Bulletin. 2023. 6 (2). P. 19 – 28.