Keywords: leaf litter

INTENSIFICATION OF THE COAGULATING SUSPENSION EFFECT ON THE EMULSION OF LIPID CONCENTRATE IN WATER

Abstract
The coagulation treatment method is widely used for the effluents of various origins treatment. Substances-coagulants disrupt colloidal formations and contribute to the small particles aggregation, which leads to their precipitation and, as a consequence, a decrease in the organic substances content and the solution turbidity. The most widely used for this purpose are coagulants based on iron and aluminum. The Hermetia illucens insect is increasingly used to obtain chemical raw materials and valuable feed products for the poultry and fish cultivation. Production processes generate effluents contaminated with biodegradable substances, including components of larval fat. In this work, it was studied the coagulation purification possibility of fat-containing effluents from the production of lipid concentrate from the Hermetia illucens fly larvae by a coagulating suspension obtained from the electric arc steel-making furnaces dust, together with a co-coagulant – chestnut leaves carbonized at 400° C, which were used to increase the number of coagulation centers in the system.
The use of a coagulating suspension in the purification of model emulsions gives a low clarification effect (49% with the addition of 0.2 cm3 per 100 cm3 of the emulsion). It was found that the addition of finely dispersed carbon-ized leaves can significantly increase the cleaning efficiency. The best result was obtained by adding the carbonized chestnut leaves in an amount of 0.3 g together with 0.2 cm3 of suspension per 100 cm3 of liquid, while the clarification efficiency of the lipid concentrate model emulsion was 98%, at a pH of 8.
The main stage of coagulation occurs in the first 40 minutes of interaction, after which no changes are observed in the state of the system under study.
PDF

STUDY OF AGGREGATIVE STABILITY OF LIPID CONCENTRATE PRODUCTION MODEL WASTE WATER AND POSSIBILITY OF ITS PURIFICATION BY SORPTION METHOD

Abstract
In the Belgorod region, work is underway to create the first high-tech large-scale production of lipid concentrate and animal protein from the larvae of the Black Soldier fly Hermetia illucens in Russia. The lipid concentrate emulsifies well in tap water, which indicates the presence of substances in it that do not belong to triglycerides of fatty acids. Obviously, it contains impurities of compounds present in the larval biomass - protein compounds and their decay products, phospholipids, etc., which can play the role of surfactants. This paper presents the results of studies on the possibility of fat-containing wastewater purification using a sorption material obtained by leaf litter of the horse chestnut genus (Aésculus hippocastanum L.) carbonization. It was found that the lipid concentrate is easily emulsified, both in pure form and in the presence of sodium lauryl sulfate. The resulting emulsions are highly resistant to degradation. It was found that the presence of the surfactant in an amount of 0.01 g/l improves the purification efficiency in the process of the model emulsion adsorption treatment. The addition of 0.6 g of the material allows to reach 92% purification, and with the addition of 1.5 g the efficiency is 98%. Similar amounts of sorbent in a pure emulsion make it possible to achieve values of only 35% and 88%, respectively. When finely dispersed particles of inorganic substances are added to an aqueous medium, the suspension effect is often observed, which manifests itself in the difference between the pH values of the suspension and the filtrate. The results of studies of the amount of added sorbent effect on pH changes in suspensions and filtrates showed that the complex «lipid micelle + sorbent» has a positive charge, and in the presence of the surfactant the charge retains a positive value, but is very close to neutral. An approach to the isoelectric point is observed.
PDF

PURIFICATION OF OILY EMULSIONS WITH LEAF LITTER OF CHERRY AND ROWAN

Abstract
The paper presents the results of a study of the possibility of using leaf litter of cherries and Rowan, widely grown in Russia, for the extraction of oil of industrial grade I-20A from aqueous media. The sorption properties of cherry leaf litter and Rowan leaf litter were also studied. The bulk density, granulometric composition, humidity, pH of the aqueous extract and losses during the calcination of CLL and RLL were determined. High efficiency of purification of water-oil emulsions is established.
PDF